Shapes of Isodensity Surfaces

Shapes of Isodensity Surfaces


    An isodensity surface is the collection of points in space where the electron density is 0.002 electrons/volume. The surface encloses the region in which there is at least a 98% probability of finding the electron. The isodensity surfaces displayed below show the volume in space in which there is at least a 98% probability of finding all of the electrons in hypochlorous acid, HOCl.

    This JAVA applet illustrates the two-dimensional shapes of the isodensity surfaces associated with atomic, yn, l, m , and hybrid orbitals. A hybird orbital is the linear combination of two or more atomic orbitals on the same atom, e.g. y(1)sp =   0.7071(2s + 2pz) and y(2)sp =   0.7071(2s - 2pz) . The lobes of the isodensity surfaces of the p and d atomic orbitals and the hybrid orbitals are displayed in different colors to denote a change in the algebraic sign of the orbital. When the isodensity surfaces for several hybrid orbitals are drawn, the smaller lobes are omitted for clarity.



Nutt 99




Dr. Nutt's CHE 115 Course