Experiment: Chemical Kinetics II


    The JAVA applet below plots the molarities of the reactant A and product B over time as the reaction

2 A     —›     B

proceeds to completion. Select an energy of activation ( Ea ) and a temperature in degrees Kelvin in the pop-up menus. Enter the initial molarity of A (value must be >= 0 and <= 5.0), and then click the "Enter" button. Plots of the molarities of A and B versus time are displayed along with the inital ( at time = 0 seconds ) rate of consumption of A (-d[A]/dt), the rate of consumption of A at 4 and 15 seconds, and the rate of formation of B (d[B]/dt) at 4 seconds.

    Use the applet in the design and performance of experiments to answer the following questions.

  1. How does the initial rate of consumption of A change with a change in the initial molarity of A?
  2. Begin by selecting Ea(1) and 298 K. Enter 5.0 M for [A]in.
  3. How and why does the rate of consumption of A change with time?
  4. Is the rate of formation of B at 4 seconds equal to the rate of consumption of A at 4 seconds?
  5. How does the initial rate of consumption of A change with a change in the energy of activation, Ea?
  6. How does the initial rate of consumption of A change with a change in the temperature?
  7. What is the rate law for the reaction?
  8. What is the value of the activation energy Ea(2)?

    Include data from your experiments to support your answers to the questions.

    If you have designed and preformed all of the experiments, answered all of the questions, and completed the report to be submitted for credit, then you may check the Answers to Chemical Kinetics II Questions



Nutt 98




Dr. Nutt's CHE 115 Course